| 手性方酰化哒嗪胺及铜(II)配合物的荧光性研究 |
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| 引用本文： | 熊俊如,向清祥,陈稼轩,张元勤.手性方酰化哒嗪胺及铜(II)配合物的荧光性研究[J].有机化学,2008,28(1):127-130. |
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| 作者姓名： | 熊俊如 向清祥 陈稼轩 张元勤 |
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| 作者单位： | 乐山师范学院化学与生命科学系,乐山,614004 |
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| 基金项目： | 四川省教育厅资助项目，四川省乐山市科技局重点项目 |
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| 摘 要： | 以3-甲基-6-氯哒嗪和α-氨基丙醇、方酸为原料合成了一种新的手性方酰化哒嗪胺衍生物和铜(II)配合物, 新化合物和铜(II)配合物结构用IR, 1H NMR及元素分析对其表征. 并对新化合物的铜(II)配合物的荧光性进行了研究.
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| 关 键 词： | 手性方酰化氨基醇 哒嗪衍生物 铜配合物 荧光性 |
| 收稿时间： | 2006-11-21 |
| 修稿时间： | 2007-07-10 |
Synthesis and Fluorescence of Chiral Pyridazine Amine of Squaic Acid and Its Copper Complex |
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| XIONG,Jun-Ru,XIANG,Qing-Xiang,CHEN,Jia-Xuan,ZHANG,Yuan-Qin.Synthesis and Fluorescence of Chiral Pyridazine Amine of Squaic Acid and Its Copper Complex[J].Chinese Journal of Organic Chemistry,2008,28(1):127-130. |
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| Authors: | XIONG Jun-Ru XIANG Qing-Xiang CHEN Jia-Xuan ZHANG Yuan-Qin |
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| Institution: | (Department of Chemistry and Life Science, Leshan Teachers College, Leshan 614004) |
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| Abstract: | A new chiral N-squaryl-N-(pyridazin-3-yl)-methyl-amine was synthesized from 3-methyl-6- chloropyridazine, alaninol and squarc acid and then its copper complex was prepared. The new compounds were confirmed by IR, 1H NMR spectra and elemental analysis. Fluorescence of the copper(II) complex was also studied. |
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| Keywords: | chiral squaric acid amidoalcohol pyridazine copper(II) complex fluorescence |
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