| Synthesis and Crystal Structure of Bi（Hsal）3（1,10- phenanthroline） （Hsal = O2CC6H4-2-OH） |
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| 引用本文： | 王永净,徐立. Synthesis and Crystal Structure of Bi（Hsal）3（1,10- phenanthroline） （Hsal = O2CC6H4-2-OH）[J]. 结构化学, 2008, 27(3): 297-300 |
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| 作者姓名： | 王永净 徐立 |
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| 作者单位： | State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou Fujian 350002 China Graduate School of the Chinese Academy of Sciences Beijing 100039 China，Fuzhou Fujian 350002 China |
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| 基金项目： | 国家重点基础研究发展计划(973计划)，国家自然科学基金 |
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| 摘 要： | A new bismuth compound Bi（Hsal）3（1,10-phenanthroline） （Hsal = O2CC6H4-2-OH） has been synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in the triclinic system, space group P1, with a = 10.243（2）, b = 11.905（3）, c = 12.934（3） A, α= 76.780（6）, β= 68.683（6）,γ= 80.930（7）°, V = 1425.6（5） A^3, Dc = 1.865 g/cm^3, Mr = 800.51, F（000） = 780, μ= 6.247 mm^-1, Z = 2, R = 0.0456 and wR = 0.1131 for 5612 observed reflections （I 〉 2σ（I））. In this compound, three salicylate ligands coordinate to the Bi atom through the carboxylate groups to form a four-membered chelate ring, and phenanthroline ligand chelates the metal through two N atoms. The structure of the title compound manifests a possible coordination mode between bismuth subsalicylate and N atom containing amino acid in the biological system.
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| 关 键 词： | 晶体 化学结构 邻二氮杂菲 分析方法 |
Synthesis and Crystal Structure of Bi(Hsal)3(1,10-phenanthroline)(Hsal=O2CC6H4-2-OH) |
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| WANG Yong-Jing,XU Li. Synthesis and Crystal Structure of Bi(Hsal)3(1,10-phenanthroline)(Hsal=O2CC6H4-2-OH)[J]. Chinese Journal of Structural Chemistry, 2008, 27(3): 297-300 |
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| Authors: | WANG Yong-Jing XU Li |
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| Affiliation: | 1. State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China;Graduate School of the Chinese Academy of Sciences,Beijing 100039,China
2. State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China |
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| Abstract: | A new bismuth compound Bi(Hsal)3(1,10-phenanthroline)(Hsal=O2CC6H4-2-OH)has been synthesized and characterized by single-crystal X-ray diffraction.It crystallizes in the triclinic system,space group P(-1),with a=10.243(2),b=11.905(3),c=12.934(3)(A),α=76.780(6),β=68.683(6),γ=80.930(7)°V=1425.6(5)(A)3,Dc=1.865g/cm3,Mr=800.51,F(000)=780,μ=6.247 mm-1,Z=2,R=0.0456 and wR=0.1131 for 5612 observed reflections(Ⅰ＞2σ(Ⅰ)).In this compound,three salicylate ligands coordinate to the Bi atom through the carboxylate groups to form a four-membered chelate ring,and phenanthroline ligand chelates the metal through two N atoms. The structure of the title compound manifests a possible coordination mode between bismuth subsalicylate and N atom containing amino acid in the biological system. |
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| Keywords: | bismuth salicylare crystal structure |
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