Synthesis, spectral characterization and redox properties of iron (II) complexes of 1-alkyl-2-(arylazo)imidazole |
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| Authors: | U S Ray D Banerjee and C Sinha |
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| Institution: | (1) Department of Chemistry, The University of Burdwan, 713 104 Burdwan, India |
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| Abstract: | Iron (II) complexes of 1-alkyl-2-(arylazo)imidazoles (p-R-C6H4-N=N-C3H2NN-1-R′, R = H (a), Me (b), Cl (c) and R′ = Me (1/3), Et (2/4) have been synthesized and formulated astris-chelates Fe(RaaiR′)
3
2+
. They are characterized by microanalytical, conductance, UV-Vis, IR, magnetic (polycrystalline state) data. The complexes
are low spin in character,t
2g
6
(Fe(II)) configurations. |
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| Keywords: | Arylazoimidazole Fe(II) complexes tris-chelates |
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