Microwave-assisted ketone-ketone rearrangement: an improved synthesis of 3-(4-alkoxyphenyl)-3- methylbutan-2-ones |
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| Authors: | Gopalakrishnan Geetha Kasinath Viswanathan Pradeep Singh N D |
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| Institution: | Centre for Natural Products, SPIC Science Foundation, 64, Mount Road, Guindy, Chennai 600 032, India. geethagopal@hotmail.com |
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| Abstract: | reaction: see text] A novel procedure for the preparation of 3-(4-alkoxyphenyl)-3-methylbutan-2-one in excellent yield is described via polymer-supported AlCl3-catalyzed rearrangement of 1-(4-ethoxyphenyl)-2,2-dimehtylpropan-1-one, followed by O-alkylation under microwave irradiation condition. |
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