A correlation of excited state rotational constants for diatomic molecules |
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| Affiliation: | 1. Department of Physics, C.M.P. Degree College, Prayagraj, Uttar Pradesh, India;2. Institute for Clean Energy Technology and Department of Physics and Astronomy, Mississippi State University, Starkville, MS, United States;3. Department of Physics, University of Allahabad, Prayagraj, Uttar Pradesh, India;1. Istanbul University, Faculty of Science, Physics Department, TR-34134 Vezneciler, Istanbul, Turkey;2. Istanbul Technical University, Faculty of Science and Letters, Physics Engineering Department, TR-34469 Maslak, Istanbul, Turkey;3. Graduate School of Engineering and Sciences, Istanbul University, TR-34452 Beyazıt, Istanbul, Turkey;4. Hochschule für Technik und Wirtschaft Berlin, Fachbereich 1, Wilhelminenhofstr. 75A, Berlin D-12459, Germany |
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| Abstract: | The concepts of “orbital stress” and “transition stress” are defined and applied to N2, N+2, CO, and CO+. The bond lengths and rotational constants of excited electronic states are related to the transition stress, and the response of the electrons and nuclei to the transition stress is shown to be a molecular property, essentially independent of the electronic configuration or state. |
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