Amination and [2,3]-sigmatropic rearrangement of propargylic sulfides using a ketomalonate-derived oxaziridine: synthesis of N-allenylsulfenimides |
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Authors: | Armstrong Alan Cooke Richard S Shanahan Stephen E |
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Affiliation: | Department of Chemistry, Imperial College London, South Kensington, London, UK. A.Armstrong@imperial.ac.uk |
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Abstract: | Amination of propargylic sulfides with a ketomalonate-derived oxaziridine under metal free conditions gives N-Boc-N-allenylsulfenimides via [2,3]-sigmatropic rearrangement. |
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