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Amination and [2,3]-sigmatropic rearrangement of propargylic sulfides using a ketomalonate-derived oxaziridine: synthesis of N-allenylsulfenimides
Authors:Armstrong Alan  Cooke Richard S  Shanahan Stephen E
Affiliation:Department of Chemistry, Imperial College London, South Kensington, London, UK. A.Armstrong@imperial.ac.uk
Abstract:Amination of propargylic sulfides with a ketomalonate-derived oxaziridine under metal free conditions gives N-Boc-N-allenylsulfenimides via [2,3]-sigmatropic rearrangement.
Keywords:
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