Let \( k \in C(R^+)\), A be a closed linear densely defined operator in the Banach space \(X\) and \( \{R(t)\}_{t\geq 0} \) be an exponentially bounded \(k\)-regularized resolvent operator families generated by A. In this paper, we mainly study pseudo k-resolvent and duality theory of k-regularized resolvent operator families. The conditions that pseudo k-resolvent become k-resolvent of the closed linear densely defined operator A are given. The some relations between the duality of the regularized resolvent operator families and the generator A are gotten. In addition, the corresponding results of duality of \(k\)-regularized resolvent operator families in Favard space are educed.