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Electrocatalytic Oxidation of Carbohydrates Mediated by Nitroxyl Radical‐modified Electrodes in Aqueous Solution
Abstract:The electrocatalytic activity of a 2,2,6,6‐tetramethylpipridine‐N‐oxyl (TEMPO)‐modified electrode toward the oxidation of carbohydrates in phosphate buffer solution was investigated under neutral aqueous solution conditions at 25 °C. The modified electrode was prepared on the surface of a glassy carbon electrode by the electrochemical polymerization of a TEMPO precursor containing a pyrrole side chain. Cyclic voltammetric studies showed that the anodic peak current increased with the concentration of carbohydrates in a dose‐dependent manner.
Keywords:TEMPO  Mediator  Electrocatalytic oxidation
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