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Palladium(0)‐Catalyzed Si—Si Bond Insertion by the Terminal Nitrogen of Diazo Compounds |
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| Abstract: | The palladium(0)‐catalyzed nitrogen insertion into cyclic Si—Si bonds has been realized by using N‐tosylhydrazones/diazo compounds as the nitrogen source. The palladium(II) nitrene formation and subsequent migratory insertion process are proposed as the key steps for this reaction. |
| Keywords: | insertion diazo compounds Si— Si bond palladium catalysts palladium(II) nitrene carbenes |