Synthesis, spectral characteristics, and crystal structure of the hexanuclear complex MeSi[η1,η5-C5H4(CO)2Fe(η1,η5-C5H5)Mn(CO)3]3 |
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| Authors: | T Yu Orlova Yu S Nekrasov P V Petrovskii M G Ezernitskaya Z A Starikova A I Yanovsky |
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| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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| Abstract: | The reaction of MeSiCl3 with 3 equivalents of LiC5H4(CO)2Fe(η1,η5-C5H4)Mn(CO)3 afforded the hexanuclear complex MeSiη1,η5-C5H4(CO)2Fe(η1,η5-C5H5)Mn(CO)3]3. The structure of the resulting complex was established by1H and13C NMR and IR spectroscopy and by X-ray diffraction analysis.
Dedicated to the memory of Academician M. I. Kabachnik on his 90th birthday.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2056–2061, October, 1998. |
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| Keywords: | “ ladder” complex crystal structure |
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