Intramolecular oxidative diamination and aminohydroxylation of olefins under metal-free conditions |
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Authors: | Kim Hyun Jin Cho Seung Hwan Chang Sukbok |
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Affiliation: | Department of Chemistry and Molecular-Level Interface Research Center, Korea Advanced Institute of Science & Technology (KAIST), Daejeon 305-701, Korea. |
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Abstract: | A metal-free procedure that is simple to operate and convenient to handle was developed for the facile intramolecular oxidative diamination of olefins using an iodobenzene diacetate oxidant and a halide additive to furnish bisindolines at room temperature. The present reaction is featured by mild conditions, a broad substrate scope, and excellent functional group tolerance. The same protocol was successfully extended to the aminohydroxylation. |
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