An eleven-vertex metallaborane with tetracapped pentagonal bipyramidal geometry |
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| Authors: | Ponniah S Joseph Bose Shubhankar Kumar Ghosh Sundargopal |
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| Institution: | Department of Chemistry, Indian Institute of Technology Madras, Chennai, India. |
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| Abstract: | A metallaborane of novel structure, (Cp*Mo)(2)B(3)H(3)Se(2){Fe(CO)(2)}(2){Fe(CO)(3)}(2)] (2; Cp* = η(5)-C(5)Me(5)), with tetracapped pentagonal bipyramidal geometry, isolated from the reaction of (Cp*Mo)(2)B(4)H(4)Se(2)], 1 with Fe(2)(CO)(9)]; the title compound exhibit an 11-vertex closo-cage geometry, having eight skeletal electron pairs (sep) and 98 valence electrons, appropriate for its geometric structure. |
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