Chiroptical generation and inversion during the mirror-symmetry-breaking aggregation of dialkylpolysilanes due to limonene chirality |
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Authors: | Nakano Yoko Ichiyanagi Fumiko Naito Masanobu Yang Yonggang Fujiki Michiya |
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Affiliation: | Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara 630-0192, Japan. |
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Abstract: | We observed the emergence and inversion of chiroptical handedness in three chiroptically silent dialkylpolysilanes during aggregation in limonene-methanol-THF tersolvents. |
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