A family of ferrocene-rich Mn7, Mn8 and Mn13 clusters |
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| Institution: | Department of Chemistry, University of Florida, Gainesville, FL 32611-7200, USA;Department of Chemistry, University of Florida, Gainesville, FL, USA |
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| Abstract: | The use of ferrocene-1,1′-dicarboxylic acid (fdcH2) in Mn cluster chemistry has led to a family of ferrocene-rich Mn7, Mn8 and Mn13 clusters. The complexes are all mixed-valence. Solid-state DC and AC magnetic susceptibility studies have established the Mn7, Mn8 and Mn13 complexes to possess S = 2, 5 and 9/2 ground states, respectively. |
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