The quest for magnets composed of vanadium and 1,4-benzoquinones |
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| Affiliation: | Department of Chemistry, University of Utah, 315 S. 1400 East, RM 2020, Salt Lake City, UT 84112-0850, USA;Department of Chemistry, University of Florida, Gainesville, FL, USA |
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| Abstract: | ![]()
The reaction of Vo(CO)6 and representative quinones, A (A = benzoquinone, chloranil, 2,3-dicyano-1,4-naphthoquinone, and dihydroxy-1,4-benzoquinone), form materials of V(A)2 · zCH2Cl2 (z < 0.1) composition, which exhibits antiferromagnetic coupling and do not magnetically order above 5 K. |
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