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High-efficiency electroluminescent polymers with stable high work function metal Al and Au as cathode
Authors:Fei Huang
Institution:Institute of Polymer Optoelectronic Materials and Devices, Key Laboratory of Special Functional Materials and Advanced Manufacturing Technology, South China University of Technology, Guangzhou 510640, China
Abstract:Soluble conjugated copolymers (PFN-TPA) derived from 2,1,3-benzothiadiazole (BTDZ), triphenylamine (TPA) and 9,9-bis(3′-(N,N-dimethylamino)propyl)fluorene (DMAPF) were synthesized by palladium(0)-catalyzed Suzuki coupling reactions. Optoelectronic properties of the copolymers were characterized by UV-vis absorption, cyclic voltammetry, photoluminescence and electroluminescence. All these copolymers show excellent EL performances in the devices with Ba/Al, Al and even Au as cathode and are promising candidate for fabrication and patterning of air-stable flat panel displays.
Keywords:Light emitting diode  Electroluminescence  Polyfluorene  Cationic polyelectrolyte
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