Synthesis and cationic polymerization of oxyranyl-functionalized triphenylamine |
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| Authors: | V Andruleviciute |
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| Institution: | Department of Organic Technology, Kaunas University of Technology, Radvilenu plentas 19, LT-50254 Kaunas, Lithuania |
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| Abstract: | Synthesis and cationic polymerization of N-{4-(oxiranylmethoxy)methyl]phenyl}-N,N-diphenylamine is reported. Diaryliodonium salts and iron-arene complex were used as photoinitiators. Iodonium salts have appeared to be much more effective photoinitiators for polymerization of the monomer than iron-arene complex. The effect of the temperature on the rate of photopolymerization of the monomer with iron-arene complex has been studied. |
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| Keywords: | Photopolymerization Epoxide Triphenylamine Iodonium salt Iron-arene complex |
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