Bathochromic shift of the fluorescence spectral maximum with increasing generation of dansyl labeled Newkome type dendrimers

Dansyl moiety attached to the core of Newkome-type dendrimers shows a bathochromic shift of the fluorescence emission spectrum with increase in dendrimer generation. However the E_T(30) plots in different solvents show a decrease in slope with increasing generation. This has been explained in terms of modification of transition energies and progressive shielding of the fluorophore with increasing generation.