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TCNQ修饰的金/18硫醇-卵磷脂双层膜在Fe(CN)_6~(3-/4-)溶液中的单向导电性
引用本文:刁鹏,蒋殿录,崔晓莉,顾登平,童汝亭,钟炳. TCNQ修饰的金/18硫醇-卵磷脂双层膜在Fe(CN)_6~(3-/4-)溶液中的单向导电性[J]. 河北师范大学学报(自然科学版), 1999, 0(2)
作者姓名:刁鹏  蒋殿录  崔晓莉  顾登平  童汝亭  钟炳
作者单位:中国科学院山西煤炭化学研究所,河北师范大学化学系
摘    要:固体支撑的双层类脂膜不仅是研究和模拟发生在生物膜上各种过程的重要模型,而且也成为研制生物分子电子器件的重要工具.在固体支撑的双层类脂膜中,金/硫醇-类脂双层膜以其缺陷少、稳定性高等特性而倍受关注[1].本文报道了修饰7,7,8,8-四氰基奎诺二甲烷(...

关 键 词:电化学;双层类脂膜;交流阻抗谱;循环伏安法;单向导电性

One Direction Conductivity of TCNQ Modified Au/Thiol Lipid Bilayer in Fe(CN) 3 /4 6 Solution
DIAO Peng ,,JIANG Dian lu ,CUI Xiao li ,,GU Deng Ping ,TONG Ru ting ,Zhong Bing. One Direction Conductivity of TCNQ Modified Au/Thiol Lipid Bilayer in Fe(CN) 3 /4 6 Solution[J]. Journal of Hebei Normal University, 1999, 0(2)
Authors:DIAO Peng     JIANG Dian lu   CUI Xiao li     GU Deng Ping   TONG Ru ting   Zhong Bing
Affiliation:DIAO Peng 1,2,JIANG Dian lu 1,CUI Xiao li 1,2,GU Deng Ping 1,TONG Ru ting 1,Zhong Bing 2
Abstract:The Au supported octadecanethiol phosphatidylcholine bilayers embedded with TCNQ(7,7,8,8 tetracyanoquinodimethane)were investigated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS).EIS indicates that the Faraday resistance of the unmodified bilayers is 5 times greater than that of TCNQ modified bilayers in Fe(CN) 3 /4 6 solution.CV shows that the modified bilayers exhibit an increase in conductance in one direction.
Keywords:electrochemistry  bilayer lipid membrane  electrochemical impedance sp ectroscopy  cyclic voltammetry  one direction conductivity
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