| A new free recoverable and reusable mono-alkaloid-type ligand and its use in preparation of ethyl （2R,3S）-2,3-dihydroxy-3-phenylpropionate |
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| 作者姓名： | Qiao Feng Wang Hui Chen Yan Zhao Xiao Ye Li Sheng Yong Zhang |
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| 作者单位： | Research Center of Chirotechnology, Fourth Military Medical University, Xi'an, 710032, PR China |
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| 基金项目： | supported by the National Natural Science Foundation of China(No.20572131,20842007);;Natural Science Basic Research Plan in Shaanxi Province of China(No.SJ08-ZT02) for financial support. |
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| 摘 要： |
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| 关 键 词： | 可重复使用 乙酸乙酯 生物碱类 3S技术 可回收 二羟基 配体 免费 |
| 收稿时间： | 13 November 2008 |
A new free recoverable and reusable mono-alkaloid-type ligand and its use in preparation of ethyl(2R,3S)-2,3-dihydroxy-3-phenylpropionate |
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| Qiao Feng Wang,Hui Chen,Yan Zhao,Xiao Ye Li,Sheng Yong Zhang.A new free recoverable and reusable mono-alkaloid-type ligand and its use in preparation of ethyl(2R,3S)-2,3-dihydroxy-3-phenylpropionate[J].Chinese Chemical Letters,2009,20(7):763-766. |
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| Authors: | Qiao Feng Wang Hui Chen Yan Zhao Xiao Ye Li Sheng Yong Zhang Research Center of Chirotechnology Fourth Military Medical University Xi'an PR China |
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| Institution: | Research Center of Chirotechnology, Fourth Military Medical University, Xi'an, 710032, PR China |
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| Abstract: | A new free recoverable and reusable mono-alkaloid-type ligand has been synthesized by a simple method.With highly polar groups,the ligand can be recycled and reused eight times to prepare ethyl(2R,3S)-2,3-dihydroxy-3-phenylpropionate with high yield and ee via asymmetric dihydroxylation(AD) reaction. |
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| Keywords: | Cinchona alkaloid Recoverable and reusable ligand Ethyl (2R 3S)-2 3-dihydroxy-3-phenylpropionate |
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