ESR spin-trapping study of radicals produced by donor-acceptor interactions |
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Authors: | L Sümegi A Rockenbauer M Györ and T Szymanska-Buzar |
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Institution: | (1) International Laboratory, Central Research Institute for Chemistry of the Hungarian Academy of Sciences, P. O. Box 17, H-1525 Budapest, Hungary;(2) Institute of Chemistry, University of Wroclaw, 50-383 Wroclaw, Poland |
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Abstract: | Nitroso compounds, well known as spin traps, have not been applied for scavenging free radicals formed in reactions with the contribution of chloranil, so far. In our studies we show that spin traps such as nitrosodurene (ND), 2,6-dichloronitrosobenzene (Cl2NB) react with radicals formed in the reaction between chloranil and durene, yielding stable spin adducts.
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![acy](/content/v157u70l614p6632/xxlarge1072.gif) ![dcy](/content/v157u70l614p6632/xxlarge1076.gif) ![icy](/content/v157u70l614p6632/xxlarge1080.gif) ![kcy](/content/v157u70l614p6632/xxlarge1082.gif) ![acy](/content/v157u70l614p6632/xxlarge1072.gif) ![lcy](/content/v157u70l614p6632/xxlarge1083.gif) , ![ocy](/content/v157u70l614p6632/xxlarge1086.gif) ![bcy](/content/v157u70l614p6632/xxlarge1073.gif) ![rcy](/content/v157u70l614p6632/xxlarge1088.gif) ![acy](/content/v157u70l614p6632/xxlarge1072.gif) ![zcy](/content/v157u70l614p6632/xxlarge1079.gif) ![ucy](/content/v157u70l614p6632/xxlarge1091.gif) ![yucy](/content/v157u70l614p6632/xxlarge1102.gif) ![shchcy](/content/v157u70l614p6632/xxlarge1097.gif) ![icy](/content/v157u70l614p6632/xxlarge1080.gif) ![iecy](/content/v157u70l614p6632/xxlarge1077.gif) ![scy](/content/v157u70l614p6632/xxlarge1089.gif) ![dcy](/content/v157u70l614p6632/xxlarge1076.gif) ![acy](/content/v157u70l614p6632/xxlarge1072.gif) ![ncy](/content/v157u70l614p6632/xxlarge1085.gif) ![ncy](/content/v157u70l614p6632/xxlarge1085.gif) ![ocy](/content/v157u70l614p6632/xxlarge1086.gif) ![rcy](/content/v157u70l614p6632/xxlarge1088.gif) ![iecy](/content/v157u70l614p6632/xxlarge1077.gif) ![acy](/content/v157u70l614p6632/xxlarge1072.gif) ![kcy](/content/v157u70l614p6632/xxlarge1082.gif) ![tscy](/content/v157u70l614p6632/xxlarge1094.gif) ![icy](/content/v157u70l614p6632/xxlarge1080.gif) .
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