Synthesis of TiO2/CNT Composites and its Photocatalytic Activity Toward Sudan (I) Degradation |
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Authors: | Amat Miribangul Xiaoli Ma Chen Zeng Huan Zou Yahui Wu Tengpeng Fan Zhi Su |
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Institution: | College of Chemistry and Chemical Engineering, Xinjiang Normal University, Urumqi, Xinjiang, China |
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Abstract: | Semiconductor photocatalysis has the potential for achieving sustainable energy generation and degrading organic contaminants. In TiO2, the addition of carbonaceous nanomaterials has attracted extensive attention as a means to increase its photocatalytic activity. In this study, composites of TiO2 and carbon nanotubes (CNT) in various proportions were synthesized by the hydrothermal method. The crystalline structures, morphologies, and light absorption properties of the TiO2/CNT photocatalysts were characterized by PXRD, TEM and UV–Vis absorption spectra. The photocatalytic efficiency of the composites was evaluated by the degradation of Sudan (I) in UV–Vis light. Introducing 0.1–0.5 wt% CNT was shown to substantially improve the photoactivity of TiO2. The composite with 0.3 wt% CNT showed the best catalytic activity, and its reaction activation energy was calculated as 39.57 kJ mol?1 from experimental rates. The degradation products of Sudan (I) with different irradiation durations were characterized by Fourier transform infrared spectroscopy, and a degradation reaction process was proposed. |
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