Oxidation of 1,3-Dioxacyclanes with Oxone and Potassium Persulfate Catalyzed by 2,2,5,5-Tetramethyl-4-Phenyl-3-Imidazoline-3-Oxide-1-Oxyl |
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| Authors: | Z.F. Akbalina N.N. Kabalnova S.S. Zlotsky I.A. Grigoriev V.V. Shereshovets G.A. Tolstikov |
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| Affiliation: | (1) Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, Ufa, 450054, Russia;(2) Siberian Department of the RAS, Novosibirsk Institute of Organic Chemistry, 9 prosp. Lavrentieva, Novosibirsk, 630090, Russia |
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| Abstract: | The catalytic effect of 2,2,5,5-tetramethyl-4-phenyl-3-imidazoline-3-oxide-1-oxyl on the oxidation of 2-isopropyl-1,3-dioxolane, 2-phenyl-1,3-dioxolane, 2-phenyl-4-chlormethyl-1,3-dioxolane, 2-isopropyl-1,3-dioxane, 2-isopropyl-4-methyl-1,3-dioxane, 2-phenyl-1,3-dioxane, 2-phenyl-4-methyl-1,3-dioxane with oxone and potassium persulfate is reported. The corresponding glycol monoesters were obtained with yields of 90-100%. |
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| Keywords: | Catalysis nitroxyl radicals cyclic acetals oxidation oxone potassium persulfate |
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