Structural thermodynamic characteristics and intermolecular interactions in aqueous solutions of hexamethylphosphorotriamide |
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| Authors: | A. M. Zaichikov M. A. Krest’yaninov |
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| Affiliation: | 1.Ivanovo State University of Chemical Technology,Ivanovo,Russia;2.Institute of Solution Chemistry,Russian Academy of Sciences,Ivanovo,Russia |
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| Abstract: | Structural thermodynamic parameters of aqueous solutions of hexamethylphosphorotriamide are calculated. They are discussed together with previously obtained data on aqueous solutions of disubstituted amides of carboxylic acids. The specific and non-specific components of the total energy of intermolecular interactions are determined. The boundaries of concentration regions with different structural organizations of solutions are found, and the preferential solvation parameters of solution components are estimated. |
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