Variational localized-site cluster expansions. VIII. Projection of spin symmetries |
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Authors: | D. J. Klein,M. A. Garcí a-Bach |
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Abstract: | We investigate the total spin structure of an approximate localized-site wave function for a collection of paramagnetic sites interacting so as to favor a singlet ground state. As the number of sites becomes infinite we obtain the distribution of weights of the different symmetry components of the localized site wave function; further, although only a very small fraction of such nonsymmetric wave functions is actually singlet, we find that it generally yields the same bulk property expectation values as its singlet-projected component. |
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