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Electrolytic sample pretreatment in atomic spectrometry: A review
Authors:Ernest Beinrohr
Affiliation:(1) Department of Analytical Chemistry, Slovak Technical University, SK-821 37 Bratislava, Slovakia
Abstract:The use of electrolysis in analytical atomic spectrometry is reviewed. Topics such as electrodeposition for analyte enrichment, electrochemical sample pretreatment and hydride generation are discussed. The use of batch and flow-through electrochemical cells is compiled and critically evaluated. Flow-through cells with porous working electrodes were found to provide the best performance for analyte enrichment.
Keywords:review  electrodeposition  electrolysis  preconcentration  atomic spectrometry
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