| Abstract: | Bis[bis(trimethylsilyl)amino]sulfane. 2. Crystal and Molecular Structure The title compound [(CH3)3Si]2N? S? N[Si(CH3)3]2 crystallizes with Z = 4 in the monoclinic space group A2/a (Nr. 15) with cell dimensions a = 22.436(4) Å, b = 6.434(5) Å, c = 17.089(6) Å, β = 117.66(2)º. For 5091 independent reflections, measured at ?80°C, the structure could be refined to R = 0.079 and Rw = 0.120. The molecules are linked together by van der Waals interactions and form layers in the bc plane, in agreement with the observed cleavage along (100). |
