Boric acid: a highly efficient catalyst for transamidation of carboxamides with amines |
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Authors: | Nguyen Thanh Binh Sorres Jonathan Tran Minh Quan Ermolenko Ludmila Al-Mourabit Ali |
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Institution: | Centre de Recherche de Gif-sur-Yvette, Institut de Chimie des Substances Naturelles, CNRS, 91198 Gif-sur-Yvette Cedex, France. nguyen@icsn.cnrs-gif.fr |
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Abstract: | A novel method of transamidation of carboxamides with amines using catalytic amounts of readily available boric acid under solvent-free conditions has been developed. The scope of the methodology has been demonstrated with (i) primary, secondary, and tertiary amides and phthalimide and (ii) aliphatic, aromatic, cyclic, acyclic, primary, and secondary amines. |
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