Regioselective aminohalogenation of β-nitrostyrenes using NCS and NBS as nitrogen/halogen sources |
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基金项目: | supported by the National Natural Science Foundation of China (Grant No.20772056,to YP);;the Welch Foundation (D-1361,to GL);;supported by the Qing-Lan Program of Jiangsu Province (to YP);;the Kua-Shi-Ji Program of the Education Ministry of China (to YP) |
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摘 要: | Aminohalogenation reaction of β-nitrostyrenes with N-halosuccinimides(N-chloro and N-bromosuccinimides) has been successfully conducted by using nickel acetate as a catalyst in the presence of potassium carbonate and succinimide as co-additives.The reaction was easily performed at room temperature under nitrogen gas protection to give dihalorinaed haloamino products in good to excellent yields(60%-98%).The structure has been confirmed by X-ray crystal structure analysis.
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关 键 词: | aminohalogenation vicinal haloamines β-nitrostyrenes NBS NCS |
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