Rapid phosphorus triester hydrolysis catalyzed by bimetallic tetrabenzimidazole complexes |
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| Authors: | Klinkel Kortney L Kiemele Lauren A Gin Douglas L Hagadorn John R |
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| Institution: | Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado, USA. |
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| Abstract: | Bimetallic complexes based on the binucleating ligand N,N,N',N'-tetrakis(2-benzimidazolyl)methyl]-2-hydroxy-1,3-diaminopropane (1L) and its new toluoyl ester derivative (2L) catalyze the hydrolysis of phosphorus triesters at ambient temperature with activities rivalling the fastest known systems. |
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