A pi-stacked 1,2,3-dithiazolyl radical. Preparation and solid state characterization of (Cl2C3NS)(ClC2NS2) |
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| Authors: | Beer Leanne Cordes A Wallace Haddon Robert C Itkis Mikhail E Oakley Richard T Reed Robert W Robertson Craig M |
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| Affiliation: | Department of Chemistry, University of Waterloo, Waterloo, Ontario, Canada N2L 3G1. |
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| Abstract: | Crystals of (Cl2C3NS)(ClC2NS2), an isothiazolyl-substituted 1,2,3-dithiazolyl radical, consist of evenly spaced, slipped pi-stacks; magnetic and conductivity measurements indicate the material is a Mott insulator with sigma RT = 2 x 10(-7) S cm-1. |
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