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The probabilistic-informational opacity functional,Jaynes's principle,and distances to equilibrium of an evolving system
Authors:François Schächter
Institution:(1) Laboratoire de Physiologie Cellulaire, Université Pierre et Marie Curie, Paris, France;(2) National Institute of Health, Bethesda, Maryland, USA
Abstract:A new probabilistic-informational concept, earlier constructed by Mugur-Schächter, is further developed. Associated with Jaynes's principle, this concept permits one to define a measure for the distance between the state of a system evolving under stable constraints and the equilibrium with these constraints. An illustration is given for a gas evolving in a thermostated box. It appears that the free energy of the gas estimates the distance to equilibrium, the estimation being defined in abstract informational-probabilistic terms.
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