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Cyclopropanation and epoxidation of 1,2-distannylalkenes and 1-silyl-2-stannylalkenes
Authors:T. N. Mitchell  B. Kowall
Affiliation:

Fachbereich Chemie, Universität Dortmund, D-44221, Dortmund, Germany

Abstract:Cyclopropanation of the title compounds is possible under certain conditions (CH2I2---Sm (Hg)) in special cases, but epoxidation is apparently a general reaction which occurs readily in a stereospecific manner when they are treated with m-chloroperbenzoic acid.
Keywords:Tin   Silicon   Cyclopropanation   Epoxidation
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