Structure of N-(1-silatranylmethyl) and N-(trimethoxysilyl-methyl) derivatives of nitrogen-containing heterocycles according to data of NMR, IR, and UV spectroscopy |
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Authors: | M G Voronkov L I Larina Yu I Bolgova O M Trofimova N F Chernov V A Pestunovich |
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Institution: | (1) Irkutsk A. E. Favorskii Institute of Chemistry, Siberian Branch, Russian Academy of Sciences (SO RAN), Irkutsk, 664033 |
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Abstract: | The 1H, 13C, 15N, and 29Si NMR, IR, and UV spectra of N-(1-silatranylmethyl) and N-(trimethoxysilylmethyl) derivatives of nitrogen heterocycles have
been studied. The dependence and interrelation of the chemical shifts of 29Si and 15N nuclei of the silatranyl group in the spectra of N-(1-silatranylmethyl)-substituted nitrogen heterocycles are determined
by the nature of the heterocyclic system.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1857–1865, December, 2006. |
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Keywords: | N-(1-silatranylmethyl) derivatives of nitrogen-containing heterocycles silatranes triethanolamine NMR spectroscopy |
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