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Structure of N-(1-silatranylmethyl) and N-(trimethoxysilyl-methyl) derivatives of nitrogen-containing heterocycles according to data of NMR, IR, and UV spectroscopy
Authors:M G Voronkov  L I Larina  Yu I Bolgova  O M Trofimova  N F Chernov  V A Pestunovich
Institution:(1) Irkutsk A. E. Favorskii Institute of Chemistry, Siberian Branch, Russian Academy of Sciences (SO RAN), Irkutsk, 664033
Abstract:The 1H, 13C, 15N, and 29Si NMR, IR, and UV spectra of N-(1-silatranylmethyl) and N-(trimethoxysilylmethyl) derivatives of nitrogen heterocycles have been studied. The dependence and interrelation of the chemical shifts of 29Si and 15N nuclei of the silatranyl group in the spectra of N-(1-silatranylmethyl)-substituted nitrogen heterocycles are determined by the nature of the heterocyclic system. __________ Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1857–1865, December, 2006.
Keywords:N-(1-silatranylmethyl) derivatives of nitrogen-containing heterocycles  silatranes  triethanolamine  NMR spectroscopy
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