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Copper(II) coordination compounds with 2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzdiazepin-1-yl)acetohydrazide and products of its condensation with pyruvic acid
Authors:A. V. Pulya  I. I. Seifullina  L. S. Skorokhod  N. N. Efimov  E. A. Ugolkova  V. V. Minin
Abstract:Some methods for the synthesis of copper(II) complexes with 2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)acetohydrazide (Hydr) ([Cu(Hydr)(H2O)Cl2]) and products of its condensation with pyruvic acid ([Cu(HydrHPv)(H2O)Cl2] and, with alkalization to pH 8, [Cu(HydrPv)2]) were developed, and the complexes themselves were synthesized. The complexes were characterized by electrical conductivity, magnetic susceptibility, and IR and EPR spectroscopy measurements.
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