Intramolecular participation in alkoxycarbenium ion pools |
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| Authors: | Suga Seiji Suzuki Shinkiti Yoshida Jun-ichi |
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| Institution: | Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan. |
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| Abstract: | reaction: see text] Alkoxycarbenium ions having no substituents on the cationic carbon have been accumulated as "cation pools" by the introduction of an ether group in an appropriate position. Intramolecular participation of the ether oxygen is suggested to be responsible for stabilization of the alkoxycarbenium ions. |
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