Synthesis,structures, and properties of bis(4,6-disubstituted 1,3,5-triazin-2-yl) ethers |
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Authors: | Mikhailichenko S. N. Chesnyuk A. A. Konyushkin L. D. Zaplishnyi V. N. |
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Affiliation: | (1) Kuban State Agricultural University, 13 ul. Kalinina, 350044 Krasnodar, Russian Federation;(2) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation |
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Abstract: | Reactions of (4,6-disubstituted 1,3,5-triazin-2-yl)trimethylammonium chlorides with glycine sodium salt in the presence of Et3N afforded bis(triazin-2-yl) ethers instead of the expected triazinylaminoacetic acids. The structures of the resulting compounds were established by the independent synthesis, spectroscopic data, and X-ray diffraction analysis. |
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Keywords: | (4,6-disubstituted 1,3,5-triazin-2-yl)trimethylammonium chlorides 4,6-dimorpholino-2-oxo-1,2-dihydro-1,3,5-triazine bis(triazin-2-yl) ethers |
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