Poly[[(μ2‐4,4′‐bipyridine)(μ3‐5‐isonicotinamidoisophthalato)cobalt(II)] trihydrate] |
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Authors: | Yi‐Fang Deng Jin‐Sheng Xu Man‐Sheng Chen Chun‐Hua Zhang |
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Abstract: | In the title compound, {Co(C14H8N2O5)(C10H8N2)]·3H2O}n, the CoII cation is five‐coordinated with a slightly distorted trigonal–bipyramidal geometry, and the 5‐isonicotinamidoisophthalate ligands link CoII atoms into a layered structure. These two‐dimensional arrays are further pillared by rod‐like 4,4′‐bipyridine ligands to give a three‐dimensional framework with pcu (primitive cubic) topology. The magnetic and adsorption properties of the title compound are also discussed. |
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