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Poly[di‐μ‐aqua‐[μ6‐N‐(4‐bromophenylsulfonyl)dithiocarbimato]dipotassium] and poly[di‐μ‐aqua‐[μ4‐N‐(4‐iodophenylsulfonyl)dithiocarbimato]dipotassium]
Authors:Jan Janczak  Mayura M M Rubinger  Leandro C Alves  Marcelo R L Oliveira
Abstract:The rigid organic linkers N‐(4‐bromophenylsulfonyl)dithiocarbimate(2?) and N‐(4‐iodophenylsulfonyl)dithiocarbimate(2?) crystallize with two potassium cations and two water molecules in their asymmetric units, forming the title coordination polymers, K2(C7H4BrNO2S3)(H2O)2]n and K2(C7H4INO2S3)(H2O)2]n. The anions and the water molecules link the potassium cations into broad two‐dimensional networks, which are further linked by K...halide interactions.
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