Abstract: | The rigid organic linkers N‐(4‐bromophenylsulfonyl)dithiocarbimate(2?) and N‐(4‐iodophenylsulfonyl)dithiocarbimate(2?) crystallize with two potassium cations and two water molecules in their asymmetric units, forming the title coordination polymers, K2(C7H4BrNO2S3)(H2O)2]n and K2(C7H4INO2S3)(H2O)2]n. The anions and the water molecules link the potassium cations into broad two‐dimensional networks, which are further linked by K...halide interactions. |