Calculation of the molecular exchanging energy of binary surfactants system on the surface monolayer of aqueous solution |
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摘 要: | By using the binary anionic/cationic surfactants system CH3(CH2)nOSO_3/CH3(CH2)nN (CH3)3 as an ex-ample, the molecular exchanging energy (ε) of adsorption on the surface monolayer of aqueous solu-tion has been studied. ε can be obtained with two methods. One is from the relationship between ε and the molecule interaction parameter (β). This relationship is founded by considering that the adsorption of mixed surfactants on the surface monolayer of solution satisfies the dimensional crystal model condition under which β can be obtained by testing the surface tension of solution. The other is directly from the molecular structure of surfactants with the Lennard-Jones formula. The results for the studied system show that these two methods coincide well.
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收稿时间: | 4 July 2004 |
修稿时间: | 22 May 2007 |
Calculation of the molecular exchanging energy of binary surfactants system on the surface monolayer of aqueous solution |
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Authors: | Wang ZhengWu Yi XiZhang |
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Institution: | 1. Department of Food Sciences & Technology, School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China 2. Institute of Theoretical Chemistry, Shandong University, Jinan 250100, China |
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Abstract: | By using the binary anionic/cationic surfactants system CH3(CH2)nOSO
3
−
/CH3(CH2)nN+(CH3)3 as an example, the molecular exchanging energy (ɛ) of adsorption on the surface monolayer of aqueous solution has been studied. ɛ can be obtained with two methods. One is from the relationship between ɛ and the molecule interaction parameter (β). This relationship is founded by considering that the adsorption of mixed surfactants on the surface monolayer of solution
satisfies the dimensional crystal model condition under which β can be obtained by testing the surface tension of solution. The other is directly from the molecular structure of surfactants
with the Lennard-Jones formula. The results for the studied system show that these two methods coincide well.
Supported by the National Natural Science Foundation of China (Grant Nos. 20676051 and 20573034) and the Important Construction
Project (Category A) of Shanghai Jiao Tong University (Grant No. AE 150085) |
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Keywords: | surfactant molecule exchanging energy dimensional crystal model |
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