| 电化学合成1, 4-双[2-(3, 4, 5-三甲氧基苯基)乙烯基]苯 |
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| 引用本文： | 邱锡元.电化学合成1, 4-双[2-(3, 4, 5-三甲氧基苯基)乙烯基]苯[J].有机化学,2000,20(3):348-351. |
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| 作者姓名： | 邱锡元 |
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| 作者单位： | 福州大学侨兴轻工业学院,福州,350002 |
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| 基金项目： | 福建省自然科学基金资助课题。 |
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| 摘 要： | 1,4-双2-(3,4,5-三甲氧基苯基]苯简称HPV]采用有机电化学的方法合成,对合成的原理和方法进行研究和探讨,得到此化合物的三种异构体的淡黄色混合物,即含29.4%全顺式,44.7%顺-反式和25.9%全顺式。所得混合物熔点范围为103-155℃,总得率为92%。
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| 关 键 词： | 电化学合成 甲氧基 苯P 苯乙烯基 有机电解合成 导电高聚物 电解槽 |
| 修稿时间： | 1999-06-02 |
Study of electroorganic synthesis of 1, 4-bis[2-(3, 4, 5- trimethoxyphenyl)vinyl] benzene |
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| QIU Xi-Yuan.Study of electroorganic synthesis of 1, 4-bis[2-(3, 4, 5- trimethoxyphenyl)vinyl] benzene[J].Chinese Journal of Organic Chemistry,2000,20(3):348-351. |
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| Authors: | QIU Xi-Yuan |
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| Institution: | QIU Xi-Yuan
(College of Light Induatry, Fuzhou University, 350002 Fuzhou) |
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| Abstract: | 1, 4-bis2-(3, 4, 5-trimethoxyphenyl)vinyl]benzene (abbreviated as HPV), one of the organic conducting materials, was synthesized by electro-reductively promoted Wittig reaction. A cylindrical sleeve cell with a diaphragm was used. The product was determined to be a light yellow mixture of three kinds of isomers of the title compound, 29.4% cis-cis, 44.7% cis-trans, 25.9% trans-trans isomers. The yield of the product was 92%, m.p. 103-155℃. |
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| Keywords: | electroorganic synthesis Wittig reaction indirect reaction system HPV Cylindrical sleeve cell |
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