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Effect of silicon compounds on the pyrolysis of propane-butane hydrocarbon mixture
Authors:V M Shekunova  I I Didenkulova  E I Tsyganova  Yu A Aleksandrov
Institution:1.Research Institute of Chemistry,Lobachevskii Nizhny Novgorod National Research University,Nizhny Novgorod,Russia;2.Lobachevskii Nizhny Novgorod National Research University,Nizhny Novgorod,Russia
Abstract:The effect of silicon-containing catalysts on the pyrolysis of propane-butane hydrocarbon mixture in a flow system was studied in the temperature range 500–850°C, the rate of the gas mixture flow 50–100 ml min−1, contact time 0.1–12.0 s, and the value of the heterogeneity factor 0.1–2.1×107 cm−1. The catalytic activity of different systems under similar conditions was compared, and the influence of various factors on the yield of ethylene and propylene was studied. The most active silicon-containing catalyst for the pyrolysis of propane-butane hydrocarbon mixture was found.
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