Structural reassignment of the alleged 6-hydroxy-1,2,4-triazine-3,5-(2H,4H)dione |
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Authors: | Thomas J Schuan Timothy J Sanford It L White Nelson J Miles |
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Abstract: | The reaction of 6-amino-1,2,4-triazine-3,5-(2H,4H)clione with sodium hydroxide or nitrous acid has been shown to give 5-hydroxy-1,2,4-triazole-3-carboxylic acid instead of 6-hydroxy-1,2,4-triazine-3,5-(2H,4H)dione as reported in the literature. The triazolecarboxylic acid was also obtained from the aminotriazine and hydrochloric acid. |
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