| 4'-(丹磺酰氨基)苯并冠醚和4'-[α-(丹磺酰氨基)乙基]苯并-15-冠-5的合成 |
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| 引用本文： | 黄枢,田宝芝. 4'-(丹磺酰氨基)苯并冠醚和4'-[α-(丹磺酰氨基)乙基]苯并-15-冠-5的合成[J]. 化学学报, 1988, 46(6): 604-607 |
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| 作者姓名： | 黄枢 田宝芝 |
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| 作者单位： | 四川大学化学系 |
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| 摘 要： | 从B12C4, B15C5和B18C6经过硝化、催化氢化和丹磺酰化合成了三种4'-(丹磺酰氨基)苯并冠醚, 从B15C5径乙酰化, Leuckart反应和丹磺酰化合成了另一个4'-[α-(丹磺酰氨)乙基]苯并-15-冠-5这些丹磺酰氨衍生物均为新荧光冠醚.
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| 关 键 词： | 二甲胺P 特效试剂 叔胺 酰胺 冠式化合物 苯P 电子密度 萘磺酸P |
Synthesis of 4'-(dansylamino)benzo crown ethers and 4'-[-(dansylamino)ethyl]-benzo-15-crown-5 |
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| HUANG SHU,TIAN BAOZHI. Synthesis of 4'-(dansylamino)benzo crown ethers and 4'-[-(dansylamino)ethyl]-benzo-15-crown-5[J]. Acta Chimica Sinica, 1988, 46(6): 604-607 |
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| Authors: | HUANG SHU TIAN BAOZHI |
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| Abstract: | Three 4'-(dansylamino)benzo crown ethers I (n = 1, 2, 3) have been synthesized from B12C4, B15C5, and B18C6 via nitration, catalytic hydrogenation and dansylation successively. The other one, 4'-[a-(dansylamino)ethyl]benzo-15-crown-5, has also been synthesized but from B15C5 via acetylation, Leuckart reaction and dansylation. These dansylamino derivatives are new species of fluorescent crown ethers. |
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| Keywords: | DIMETHYLAMINE P SPECIFIC REAGENTS TERTIARY AMINE AMIDES CROWN ETHER COMPOUNDS BENZENE P ELECTRON DENSITY NAPHTHALENESULFONIC ACID P |
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