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Direct Visualization of the Chemical Mechanism in SERRS of 4‐Aminothiophenol/Metal Complexes and Metal/4‐Aminothiophenol/Metal Junctions
Authors:Mengtao Sun Prof Dr  Hongxing Xu  Prof Dr
Institution:1. Beijing National Laboratory for Condensed Matter Physics and Laboratory of Soft Matter Physics, Institute of Physics, Chinese Academy of Sciences, P. O. Box 603‐146, Beijing, 100190 (P. R. China), Fax: (+86)?10‐82649228;2. Division of Solid State Physics, Lund University, Lund 22100 (Sweden)
Abstract:Direct visualization of photoinduced tunneling charge transfer (TCT) in an Au5/para‐aminothiophenol (PATP)/Ag6 junction in which Au and Ag clusters form the first and second layer, respectively, is provided by the charge difference density (see picture; green and red stand for holes and electrons, respectively).
image

Keywords:charge transfer  density functional calculations  Raman spectroscopy  surface‐enhanced resonance
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