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Optical Response Sensitive to the Assembly in a Molecular Material: Ultrathin Film with a Vanishing Electronic Absorption
Authors:K Rajesh  T P Radhakrishnan Prof
Institution:School of Chemistry, University of Hyderabad, Hyderabad 500?046 (India), Fax: (+91)?40‐2004‐5893
Abstract:The characteristic electronic absorption of a zwitterionic molecule arising from an intramolecular charge‐transfer transition observed in the solution and the bulk solid states vanishes completely when the molecules are assembled into mono‐ and multilayer Langmuir–Blodgett films (see figure). Microscopy and spectroscopy investigations and computational modeling provide insight into this remarkable phenomenon.
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Keywords:diaminodicyanoquinodimethane  electronic absorption  Langmuir–  Blodgett films  supramolecular chemistry
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