Torsional Photoisomerization Proceeding Adiabatically Through a Volume‐Conserving Pathway in Uninhibited Fluid Media期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Torsional Photoisomerization Proceeding Adiabatically Through a Volume‐Conserving Pathway in Uninhibited Fluid Media

Authors:	Ioanna Balomenou George Pistolis Dr.

Affiliation:	Institute of Physical Chemistry, NCSR Demokritos, 15310 Aghia Paraskevi, Athens (Greece), Fax: (+003)?2106511766

Abstract:	Doing the hula twist? A photochemically stimulated inversion of an sp²‐hybridized oxygen atom upon simultaneous rotation of two adjacent bonds may be possible in a pure singlet excited potential energy surface in uninhibited fluid media (see scheme).

Keywords:	adiabatic isomerization kinetics photochemistry