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Detection of Biologically Important Anions in Aqueous Media by Dicationic Azaborines Bearing Ammonio or Phosphonio Groups
Authors:Tomohiro Agou Dr  Masaki Sekine  Junji Kobayashi Dr  Takayuki Kawashima Prof Dr
Institution:Department of Chemistry, Graduate School of Science, The University of Tokyo, 7–3–1 Hongo, Bunkyo‐ku, Tokyo 113–0033 (Japan), Fax: (+81)?5800‐6899
Abstract:Not common sense, but specific : Dicationic azaborines bearing ammonio or phosphonio groups showed enhanced Lewis acidity as well as improved water solubility. Complexation between the azaborines and fluoride or cyanide ions was observed in aqueous media (see figure; DMSO= dimethyl sulfoxide).
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Keywords:analytical methods  azaborines  cyanides  fluorides  main group elements  sensors
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