Oxidative Addition Reactions of Element–Hydrogen Bonds with Different Polarities to a Gallium(I) Compound |
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| Authors: | Annekathrin Seifert Dominik Scheid Gerald Linti Prof. Dr. Thomas Zessin |
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| Affiliation: | Universit?t Heidelberg, Anorganisch‐Chemisches Institut, Im Neuenheimer Feld 270, 69120 Heidelberg (Germany), Fax: (+49)?6221‐546617 |
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| Abstract: | The gallium(I) derivative [Ga({N(dipp)CMe}2CH)] ( 1 ; dipp=2,6‐diisopropylphenyl) undergoes facile oxidative addition reactions with various element–hydrogen bonds including N? H, P? H, O? H, Sn? H, and H? H bonds. This was demonstrated by its reaction with triphenyltin hydride, ethanol, water, diethylamine, diphenylphosphane, and dihydrogen. All products were characterized by means of single‐crystal X‐ray structure determination, NMR spectroscopy, IR spectroscopy, and mass spectrometry. |
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| Keywords: | gallium hydrogen oxidative addition tin X‐ray diffraction |
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