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Solvent‐Assisted Organized Structures Based on Amphiphilic Anion‐Responsive π‐Conjugated Systems
Authors:Hiromitsu Maeda Prof Dr  Yoshihiro Ito  Yohei Haketa  Nazuki Eifuku  Eunji Lee  Myongsoo Lee Prof Dr  Takeshi Hashishin Dr  Kenji Kaneko Prof Dr
Institution:1. College of Pharmaceutical Sciences, Institute of Science and Engineering, Ritsumeikan University, Kusatsu 525‐8577 (Japan), Fax: (+81)?77‐561‐2659;2. PRESTO, Japan Science and Technology Agency (JST), Kawaguchi 332‐0012 (Japan);3. Center for Supramolecular Nanoassembly and Department of Chemistry, Yonsei University, Seoul 120‐749 (Korea);4. College of Life Sciences, Institute of Science and Engineering, Ritsumeikan University, Kusatsu 525‐8577 (Japan);5. Department of Materials Science and Engineering, Graduate School of Engineering, Kyushu University, Fukuoka 819‐0395 (Japan)
Abstract:Just subtract water : Amphiphilic π‐conjugated acyclic oligopyrroles form solvent‐assisted H‐aggregates that give rise to vesicular structures in aqueous solution (see figure). The H‐aggregates are sensitive to the conditions and are transformed into J‐aggregates by the removal of water.
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Keywords:amphiphiles  H‐aggregates  pyrrole derivatives  supramolecular chemistry  vesicles
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